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INDICE
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The evidence of both the analysis and the microstructure
eliminates most of the common gilding techniques. It is not
depletion gilding as there is not enough gold in the core metal to
produce that thickness of gilding and the gilding layer is too
sharply distinct from the body metal. It is not foil gilding
because it lacks the evidence of working and is very uneven in
thickness. Mercury gilding can be discounted (no mercury detected),
and electrochemical gilding (too thick and with a micro-structure
not seen in electro-deposited metals). The microstructure and the
close junction with the irregular surface of the copper indicate
that the gilding was applied molten, so it is concluded that this
is an example of what has been termed in the literature as fusion
gilding or wash gilding (Bergsoe, 1938 i Scott, 1986a and b). By
reference to the ternary Au-Ag-Cu diagram it can be calculated that
the gilding alloy of this ornament (44%Au, 56%Cu, 4%Ag) would have
been molten at about 960°C, while the copper alloy core (estimated
from analysis of the corroded metal as approximately 95%Cu, 5%Au)
would not begin to melt until the temperature reached over 1060°C.
This margin in melting temperatures of 100°C, while not great, is
sufficient to have allowed the gilding layer to be molten without
damaging the ornament.
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Photograph 15: Gilded cooper owl mace head. Moche (Peru)
(height 6.5 cm). BM 1949 Am 22.217 [photo A. Milton, British
Museum].
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The practical application of fusion gilding is still not fully
understood. It was originally identified by Bergsoe (1938) on
objects from the La Tolita area on the Pacific coast of Ecuador.
More recently, gilded sheet copper fragments from the Department of
Nariño, Colombia, have been studied by David Scott (1986, a and b).
A cast Moche mace head in the form of an owl's head from the
British Museum's collections (Photograph 15) has also been found to
have this type of gilding (Bowman et al 1997). The two methods
which have been suggested for applying this gilding are dipping the
copper object into a bath of molten gold alloy or applying the
molten alloy to the heated copper ornament and allowing it to run
over the surface. Neither of these methods would fully account for
features seen on all of this class of gilded object. There are
practical problems with dipping a copper-gold object into a molten
gold-copper-silver alloy, not least the difficulty of controlling
the temperature so that the item to be gilded does not melt in the
crucible of molten gold. There is also the problem of holding it
securely while coating the whole surface evenly. The Moche owl has
strong relief decoration, which would have been flooded by either
dipping in molten metal or running it over the surface, but the
gilding on this piece is fairly evenly distributed over the flat
areas and in the channels. How this was done is not known but
perhaps fine grains of gold alloy were applied evenly over the
surface in a paste with a flux to prevent oxidation and heated
until the grains melted.
It is quite possible that different methods were used for
different types of object. The fusion gilding of sheet metal, which
requires further forming to make a finished object might well be
applied by a different method from the fusion gilding on an object
cast to its final shape. Scott (1986a: 322) has reported sheet
copper which has been gilded on only one side, so could not
possibly have been dipped in molten metal, but on other objects he
found evidence of dipping, particularly a silvered copper
nose-ring. Whatever the method used to apply the plating, it is
apparently not a common technique. It seems to be largely confined
to the coastal areas of Ecuador, reaching at its northern extent up
into the Nariño area of Colombia and clown as far as the Moche and
Vicus regions of northern Peru. No fusion gilding has been
identified anywhere else in the world though molten silver-copper
alloy was a method used by the Celts and the Romans for plating
copper (La Niece 1993:206). How far this reflects the real limits
of the use of fusion plating, rather than the difficulty in
identifying it, remains to be seen.
The results presented here form a part of a scientific study of
the pre-Hispanic gold objects in the British Museum, which like
most such collections lack any real archaeological context. The
work is still in progress and will be published in the catalogue of
the collection. The aim is to make the technological
characteristics of the pieces available for comparison with
stylistically similar pieces elsewhere. A broad database of
analyses and manufacturing techniques will assist in the
understanding of where these objects belong and will do something
to ameliorate the loss of archaeological information.
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